Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water

Muhammad Naswir; Susila Arita; Marsi; Salni

doi:doi:10.11648/j.sjc.20130105.14

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Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water

Muhammad Naswir, Susila Arita, Marsi, Salni

Published in Science Journal of Chemistry (Volume 1, Issue 5)

Received: 2 December 2013 Published: 30 January 2014

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Abstract

Chemical composition of bentonite may undergo change if when given treatment with ion exchange or by activation. Activation that is often used is thermal activation and chemical activation, in this study used activator is 6% HCl. Bentonite is used as the sample obtained in five villages in the district. Sample preparation is done by the process of drying with sunlight and oven, then puree and add HCL at 6% for 10 hours, drained, washed with distilled water until pH> 6, dried in an oven at 120oC for 6 hours. Bentonite is already inactive characterization by means of XRD and SEM-EDS, then tested for its ability to reduce the parameters pH, color, Organic Matter, TDS and Fe in the peat water. Measurement parameters pH by using a pH meter, organic substance, color and iron (Fe) with a spectrophotometer method and gravimetric solute done. The results showed that the addition of bentonite which is activated as much as 3 ml gr/500 peat water can reduce the concentration of color 84.10%, 80.50% and the organic matter content of iron (Fe) up 79.25%, activation with HCl 6% parameter is significant in reducing water peat and bentonite are added the more the greater its ability to reduce peat water parameters. ANOVA results showed that the addition of bentonite did not affect the pH and TDS peat water well is not activated bentonite and activated on the real level λ = 0.05, this is because bentonite having a pH below 5.0 and dropped after activation with strong acids . The ability of bentonite to absorb organic substances, iron and water color on peat caused by bentonite has a layered structure, containing of silica and alumina, bentonite and colloidal power expands the strong and have cations that can be exchanged, which converge in mineneral monmorrilonit, kaolinite, quartz and cristobalit

Published in	Science Journal of Chemistry (Volume 1, Issue 5)
DOI	10.11648/j.sjc.20130105.14
Page(s)	74-82
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Bentonite, XRD, SEM-EDS, Activator, Water Peat

References

[1]	Naswir, M, Arita, S, Marsi, Salni (2013). Characterization of Bentonite with X-Ray Diffraction and Scanning Electron Microskopy Energy Dispertive Spektroskopy in usage for Removing pH, Colour, Fe and Organic Matter in Peat Water. International Journal of Clean Energy Technologies JOCET, ISSN: 1793-821 Vol. 3 Juni 2013. IACSIT Press
[2]	Grim, R.E. and Given. 1978. Bentonites, New York: Elsevier. 256 pp
[3]	Gilson, J.L 1960. Industrial Mineral and Rock, The American Institute of Mining, Metallurgical and Petroleum Engineers, New York. Third Edition
[4]	A. Perez-G, A.M., Urtiaga., R.Ibanez.,and I.Ortiz., 2012. State of the art and riview on the tretment technologies of water reverse osmosis concentarates. Journal water research 46 pp 267-283
[5]	Chalermyanot,T. and Arrkul.S. 2005. Compacted sand-bentonite mixture for hydraulic containment liners Songklanakarin J. Sci. Technol. 27 (2) pp 313-323
[6]	Manguin, G., Corsin, P., 2005. Concentrate and other wast isposal from SWRO Plants. Characterization and reduction of their enviromental impact. Desalination 182. 355-364
[7]	Iswono. 2001. Effectivites Poly Aluminium Chloride for Colour peat water in Siantan Hulu Pontiakan city. Diponegoro University
[8]	Dewi, F. dan Notodarmojo. 2007. Removal colour and organic matter with Two Stage Coagulation. Journal Teknik Lingkungan ITB , 13(1) :17-26
[9]	Eri, R. I. dan Hadi, W. 2008. The Study of Peat Water for drink water with Proces Upflow Anaerobik Filter (UAF) dan Slow Sand Filter (SSF) combination. Teknik Lingkungan FTSP-ITS Surabaya.
[10]	Said, N.I, 2005. Water treatment. http://www, kimprawil.go. id/ balitbang/pusair/air
[11]	Yusnimar. 2010. Treatment of peat water by bentonite. Journal Sains dan Teknologi Fakultas Teknik 9 (2) University of Riau; 77-81
[12]	Grim, R.E. 1968. Clay Mineralogy, 2 nd, Edittion, Mc, Graw Hill Book Company
[13]	Zulkarnaen, Wardoyo, S. Marmer, D. H. 1990. The study of bentonite treatment in Oule Trenggalek District west Java for adsorben. Buletin PPTM Vol. 12 No.6 Jakarta P. 9-12
[14]	Bradley S.M,. Kydd R.A. Yamdagri, R. Fyte C.A. 1992. Expanded Clays and Other Microporous Materials, Syntesis of Microporous Materails, Vol 2. Vans Nonstrand Reihold, New York
[15]	Zouboulis. A.I., Cha. X.L., dan Katsoyiannis. I.A., 2004. The Application of Biofloculant for The Removal of Humic Acid rom Stabilized Landfill Leachate, Enviromental Management Jornal 70, 35-41
[16]	Sukandarrumidi, 1999. The Excavation og Materials Industry. Gajah Mada of University. Press
[17]	Naswir, M dan Intan Lestari (2003). Effctivities to use bentonite and carbon active to removal ion Fe in peat water. Jambi University
[18]	Naswir, M. and Aima, H. 2008. Study of Peat Moss water for consume water with CCBN-RO Technology. Prociding. Seminar International to UNSOED Jawa Tengah
[19]	Syuhada, Rachmat Wijaya, Jayatin, dan Syaiful Rohman. 2008. Modifikasi Bentonit (Clay) Menjadi Organoclay dengan Penambahan Surfaktan. Journ. Nano sains & Nanoteknologi. BPPT pp. 48-51.

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APA Style

Muhammad Naswir, Susila Arita, Marsi, Salni. (2014). Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water. Science Journal of Chemistry, 1(5), 74-82. https://doi.org/10.11648/j.sjc.20130105.14

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ACS Style

Muhammad Naswir; Susila Arita; Marsi; Salni. Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water. Sci. J. Chem. 2014, 1(5), 74-82. doi: 10.11648/j.sjc.20130105.14

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AMA Style

Muhammad Naswir, Susila Arita, Marsi, Salni. Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water. Sci J Chem. 2014;1(5):74-82. doi: 10.11648/j.sjc.20130105.14

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@article{10.11648/j.sjc.20130105.14,
  author = {Muhammad Naswir and Susila Arita and Marsi and Salni},
  title = {Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {5},
  pages = {74-82},
  doi = {10.11648/j.sjc.20130105.14},
  url = {https://doi.org/10.11648/j.sjc.20130105.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130105.14},
  abstract = {Chemical composition of bentonite may undergo change if when given treatment with ion exchange or by activation. Activation that is often used is thermal activation and chemical activation,  in this study used activator is 6% HCl. Bentonite is used as the sample obtained in five villages in the district. Sample preparation is done by the process of drying with sunlight and oven, then puree and add HCL at 6% for 10 hours, drained, washed with distilled water until pH> 6, dried in an oven at 120oC for 6 hours. Bentonite is already inactive characterization by means of XRD and SEM-EDS, then tested for its ability to reduce the parameters pH, color, Organic Matter, TDS and Fe in the peat water. Measurement parameters pH by using a pH meter, organic substance, color and iron (Fe) with a spectrophotometer method and gravimetric solute done. The results showed that the addition of bentonite which is activated as much as 3 ml gr/500 peat water can reduce the concentration of color 84.10%, 80.50% and the organic matter content of iron (Fe) up 79.25%, activation with HCl 6% parameter is significant in reducing water peat and bentonite are added the more the greater its ability to reduce peat water parameters. ANOVA results showed that the addition of bentonite did not affect the pH and TDS peat water well is not activated bentonite and activated on the real level λ = 0.05, this is because bentonite having a pH below 5.0 and dropped after activation with strong acids . The ability of bentonite to absorb organic substances, iron and water color on peat caused by bentonite has a layered structure, containing of silica and alumina, bentonite and colloidal power expands the strong and have cations that can be exchanged, which converge in mineneral monmorrilonit, kaolinite, quartz and cristobalit},
 year = {2014}
}

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TY  - JOUR
T1  - Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water
AU  - Muhammad Naswir
AU  - Susila Arita
AU  - Marsi
AU  - Salni
Y1  - 2014/01/30
PY  - 2014
N1  - https://doi.org/10.11648/j.sjc.20130105.14
DO  - 10.11648/j.sjc.20130105.14
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 74
EP  - 82
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130105.14
AB  - Chemical composition of bentonite may undergo change if when given treatment with ion exchange or by activation. Activation that is often used is thermal activation and chemical activation,  in this study used activator is 6% HCl. Bentonite is used as the sample obtained in five villages in the district. Sample preparation is done by the process of drying with sunlight and oven, then puree and add HCL at 6% for 10 hours, drained, washed with distilled water until pH> 6, dried in an oven at 120oC for 6 hours. Bentonite is already inactive characterization by means of XRD and SEM-EDS, then tested for its ability to reduce the parameters pH, color, Organic Matter, TDS and Fe in the peat water. Measurement parameters pH by using a pH meter, organic substance, color and iron (Fe) with a spectrophotometer method and gravimetric solute done. The results showed that the addition of bentonite which is activated as much as 3 ml gr/500 peat water can reduce the concentration of color 84.10%, 80.50% and the organic matter content of iron (Fe) up 79.25%, activation with HCl 6% parameter is significant in reducing water peat and bentonite are added the more the greater its ability to reduce peat water parameters. ANOVA results showed that the addition of bentonite did not affect the pH and TDS peat water well is not activated bentonite and activated on the real level λ = 0.05, this is because bentonite having a pH below 5.0 and dropped after activation with strong acids . The ability of bentonite to absorb organic substances, iron and water color on peat caused by bentonite has a layered structure, containing of silica and alumina, bentonite and colloidal power expands the strong and have cations that can be exchanged, which converge in mineneral monmorrilonit, kaolinite, quartz and cristobalit
VL  - 1
IS  - 5
ER  -

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Author Information

Muhammad Naswir

Doctoral Program, Environmental Science Program , Graduate School , University of Sriwijaya, Jl.Padang Selasa No.524, Bukit Besar Palembang, Indonesia
Susila Arita

Faculty of Chemical Engineering Sriwijaya University, Jl.Padang Selasa No.524, Bukit Besar, Palembang, Indonesia
Marsi

Faculty of Agriculture, Sriwijaya University, Jl.Padang Selasa No.524, Bukit Besar Palembang, Indonesia
Salni

Faculty of Mathematics and Natural Science of Sriwijaya University, Jl.Padang Selasa No.524, Bukit Besar Palembang, Indonesia

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APA Style

Muhammad Naswir, Susila Arita, Marsi, Salni. (2014). Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water. Science Journal of Chemistry, 1(5), 74-82. https://doi.org/10.11648/j.sjc.20130105.14

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ACS Style

Muhammad Naswir; Susila Arita; Marsi; Salni. Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water. Sci. J. Chem. 2014, 1(5), 74-82. doi: 10.11648/j.sjc.20130105.14

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AMA Style

Muhammad Naswir, Susila Arita, Marsi, Salni. Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water. Sci J Chem. 2014;1(5):74-82. doi: 10.11648/j.sjc.20130105.14

Copy | Download

@article{10.11648/j.sjc.20130105.14,
  author = {Muhammad Naswir and Susila Arita and Marsi and Salni},
  title = {Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {5},
  pages = {74-82},
  doi = {10.11648/j.sjc.20130105.14},
  url = {https://doi.org/10.11648/j.sjc.20130105.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130105.14},
  abstract = {Chemical composition of bentonite may undergo change if when given treatment with ion exchange or by activation. Activation that is often used is thermal activation and chemical activation,  in this study used activator is 6% HCl. Bentonite is used as the sample obtained in five villages in the district. Sample preparation is done by the process of drying with sunlight and oven, then puree and add HCL at 6% for 10 hours, drained, washed with distilled water until pH> 6, dried in an oven at 120oC for 6 hours. Bentonite is already inactive characterization by means of XRD and SEM-EDS, then tested for its ability to reduce the parameters pH, color, Organic Matter, TDS and Fe in the peat water. Measurement parameters pH by using a pH meter, organic substance, color and iron (Fe) with a spectrophotometer method and gravimetric solute done. The results showed that the addition of bentonite which is activated as much as 3 ml gr/500 peat water can reduce the concentration of color 84.10%, 80.50% and the organic matter content of iron (Fe) up 79.25%, activation with HCl 6% parameter is significant in reducing water peat and bentonite are added the more the greater its ability to reduce peat water parameters. ANOVA results showed that the addition of bentonite did not affect the pH and TDS peat water well is not activated bentonite and activated on the real level λ = 0.05, this is because bentonite having a pH below 5.0 and dropped after activation with strong acids . The ability of bentonite to absorb organic substances, iron and water color on peat caused by bentonite has a layered structure, containing of silica and alumina, bentonite and colloidal power expands the strong and have cations that can be exchanged, which converge in mineneral monmorrilonit, kaolinite, quartz and cristobalit},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Activation of Bentonite and Application for Reduction pH, Color, Organic Substance, and Iron (Fe) in the Peat Water
AU  - Muhammad Naswir
AU  - Susila Arita
AU  - Marsi
AU  - Salni
Y1  - 2014/01/30
PY  - 2014
N1  - https://doi.org/10.11648/j.sjc.20130105.14
DO  - 10.11648/j.sjc.20130105.14
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 74
EP  - 82
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130105.14
AB  - Chemical composition of bentonite may undergo change if when given treatment with ion exchange or by activation. Activation that is often used is thermal activation and chemical activation,  in this study used activator is 6% HCl. Bentonite is used as the sample obtained in five villages in the district. Sample preparation is done by the process of drying with sunlight and oven, then puree and add HCL at 6% for 10 hours, drained, washed with distilled water until pH> 6, dried in an oven at 120oC for 6 hours. Bentonite is already inactive characterization by means of XRD and SEM-EDS, then tested for its ability to reduce the parameters pH, color, Organic Matter, TDS and Fe in the peat water. Measurement parameters pH by using a pH meter, organic substance, color and iron (Fe) with a spectrophotometer method and gravimetric solute done. The results showed that the addition of bentonite which is activated as much as 3 ml gr/500 peat water can reduce the concentration of color 84.10%, 80.50% and the organic matter content of iron (Fe) up 79.25%, activation with HCl 6% parameter is significant in reducing water peat and bentonite are added the more the greater its ability to reduce peat water parameters. ANOVA results showed that the addition of bentonite did not affect the pH and TDS peat water well is not activated bentonite and activated on the real level λ = 0.05, this is because bentonite having a pH below 5.0 and dropped after activation with strong acids . The ability of bentonite to absorb organic substances, iron and water color on peat caused by bentonite has a layered structure, containing of silica and alumina, bentonite and colloidal power expands the strong and have cations that can be exchanged, which converge in mineneral monmorrilonit, kaolinite, quartz and cristobalit
VL  - 1
IS  - 5
ER  -

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