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Volumetric and Viscometric Studies of Solute –Solvent and Solute-Solute Interactions of Glycine in Aqueous in Aqueous Electrolytes at 30oC

Received: 11 November 2014     Accepted: 13 November 2014     Published: 22 November 2014
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Abstract

Densities and viscosities of Glycine in aqueous NaCl and MgCl2(0.02& 0.06 M ) solutions have been determined experimentally at 30oC.The results obtained from density and viscosity measurement have been used to calculate A and B coefficients and free energies of activation of viscous flow of solvent Δ µ10# and solute Δ µ20# .The results are discussed in terms of the dehydration effect of the electrolytes upon the amino acids and weak solute- solute and strong solute- solvent interactions. The properties of these amino acids in water and water+ electrolytes solution systems are discussed in terms of the charge , size and hydrogen bonding effect.

Published in International Journal of Science, Technology and Society (Volume 3, Issue 1-2)

This article belongs to the Special Issue Academic Research for Multidisciplinary

DOI 10.11648/j.ijsts.s.2015030102.12
Page(s) 6-9
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Glycine, Aqueous Electrolytes, Jones- Dole coefficients and Free Energies of Activation

References
[1] Y. Akhtar, “Volumetric and viscometric behavior of amino acids in aqueous metal electrolytes solutions at 308 K”,Fluid Phase Equil. Vol. 258 2007 pp125-131.
[2] Y. Akhtar, J. international acad. Res. Multi Disipliry. , “Molecular and thermodynamic interactionstudies of D(+) glucose with mixed solvents of electrolytes solutions at 303K”, vol. 2 2014 pp 693-700.
[3] F. J. Millero, A. L. Surdo and C. Shiv,“Apparent molal volumes and adiabatic compressiblities of aqueous transition metals.” J. Phys. Com. Vol. 84 1980 pp719-723.
[4] S. S. Aswale, S.R. Aswalev and and R. S. Hajare,“Adiabatic compressibility intermolecular free length and acoustic relaxation time of aqueous antibiotic cefotaxime sodium” Indian J. Chem., vol.4 2012 pp2671-2677.
[5] S. Thirumaran and J. K. Sabu, “Ultrasonic studies of interactions of some alkali halides in aqueous d-glucose solutions at varying molalities and temperature”, Journal Exp. Sci., Vol. 3 2012 pp33-39.
[6] M. J. Iqbal and M. A. Chaudhry, “ Volumetric and viscometric studies of drugs in aqueous medium at different temperature”, J. Chem. Engg. Vol. 54 2009 pp 2772-2776.
[7] A. K. Nain and R. Pal. “ Study of solute- solute and solute -solvent interactions of Threonine in aqueous glucose solutions at different temperatures by using volumetric andviscometric methods”, J. ChemThermodyn. , vol.104 2013; pp 60-98.
[8] E. J Gonzalez, S. B. Bottini, S. Peeda and E. A. Macedo, “Liquid- Liquid equlibria of binary systems, Experimental data and Thermodynamic modeling using a group contribution equation of state” Fluid Phase Equil. Vol.362 2014 pp163-169.
[9] M. J. Iqbal and M. Siddiquah, “ Partial molar volume of mefenamic acid in alcohol at temperature 293.15 and 313.15 K,” J. Braz. Chem. Soc. Vol.17 2006 pp727-735.
[10] F. Ciotta, J. P. M. Truster and V. Vesovic, “ Extended hard - sphere model for the viscosity’’, Fluid Phase Equilib. Vol.363 2014 pp239-247.
[11] X. Jiang, C. Zhu and Y. Ma.“Volumetric and viscometric studies of amino acids in L-L-ascorbic acid aqueous solutions at temperature 293.15- 323.15 K”, J. Chem. Thermodyn. Vol.71 2014 pp50-63..
[12] Y. Akhtar, S. F. Ibrahim, Arabian , “Ultrasonic and thermodynamic studies of glycine in aqueous electrolytes solutions at 303 K”, J. Arabian Chem. Vol. 4 2011 pp 487- 490.
[13] R. K. Wadi and P. Ramasmi “Partialmolal volumes and adiabatic compressibility of transfer of glycine and D-L alanine from water to aqueous sodium sulphate at 288.15, 298.15 and 308.15 K”, J. Chem. Soc. Faraday Trans. Vol. 93 1997 243-247.
[14] M. S. Hussain, T. K. Biswas, D. C. Kabiraz, M. N. Islam and M. E. Haque, “Studies on sodium dodecylsulphate in aqueous and in aqueous amino acids solutions”, J. Chem. Thermodyn. Vol.71 2014; pp6-13.
[15] I.L. Shulgin and E. Ruckenstein“ Relationship between preferential interac- tion of a protein in an aqueous mixed solvent and its solubility”,Biophys Chem. Vol. 118 2005 pp128-34.
[16] Vishnu D., Y. Akhtar, J. D.Pandey, “Ultrasonic and Thermodynamic studies of Ternary solutions”,ActaAcoust. , Vol 84 1998 pp 976 981.
[17] G. Jones and M. Dole ," The viscosity of aqueous solutions of strong with special reference to barium chloride " J. Am. Chem. Soc. Vol. 51 1929 pp 2950-2964.
[18] H. Fakenhagen and E. L. Vernon ,"The viscosity of aqueous solutions of strong electrolytes solutions according to electrostatic theory" ,Phil. Mag. Vol.14(92) 1932 pp 537-565.
[19] A. W. Hakin, M. M. Duck, J. L. Marty, K. E. Preuss, J. Chem. Soc. Faraday Trans. 90 (1994)2027-2037.
[20] D. Feakins, D. J. Freemantle, K. G. Lawrence, " transition state treatment of the relative viscosity of electrolytes solutions " , J. Chem. Soc. Faraday Trans. I, Vol. 70 1974 pp 795-806.
[21] S. C. Bai, G. B. Yan , " Viscosity B-coeffecients and activation parameters for viscous flow of sucrose solution", Carbohydrates Research, Vol. 338 2003 pp 2921-2927.
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    Yasmin Akhtar. (2014). Volumetric and Viscometric Studies of Solute –Solvent and Solute-Solute Interactions of Glycine in Aqueous in Aqueous Electrolytes at 30oC. International Journal of Science, Technology and Society, 3(1-2), 6-9. https://doi.org/10.11648/j.ijsts.s.2015030102.12

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    ACS Style

    Yasmin Akhtar. Volumetric and Viscometric Studies of Solute –Solvent and Solute-Solute Interactions of Glycine in Aqueous in Aqueous Electrolytes at 30oC. Int. J. Sci. Technol. Soc. 2014, 3(1-2), 6-9. doi: 10.11648/j.ijsts.s.2015030102.12

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    AMA Style

    Yasmin Akhtar. Volumetric and Viscometric Studies of Solute –Solvent and Solute-Solute Interactions of Glycine in Aqueous in Aqueous Electrolytes at 30oC. Int J Sci Technol Soc. 2014;3(1-2):6-9. doi: 10.11648/j.ijsts.s.2015030102.12

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  • @article{10.11648/j.ijsts.s.2015030102.12,
      author = {Yasmin Akhtar},
      title = {Volumetric and Viscometric Studies of Solute –Solvent and Solute-Solute Interactions of Glycine in Aqueous in Aqueous Electrolytes at 30oC},
      journal = {International Journal of Science, Technology and Society},
      volume = {3},
      number = {1-2},
      pages = {6-9},
      doi = {10.11648/j.ijsts.s.2015030102.12},
      url = {https://doi.org/10.11648/j.ijsts.s.2015030102.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijsts.s.2015030102.12},
      abstract = {Densities and viscosities of Glycine in aqueous NaCl and MgCl2(0.02& 0.06 M ) solutions have been determined experimentally at 30oC.The results obtained from density and viscosity measurement  have been used to calculate A and  B coefficients and free energies of activation of viscous flow of solvent Δ µ10# and    solute Δ µ20# .The results are discussed in terms of the dehydration effect of the electrolytes upon the amino acids and weak solute- solute and strong solute- solvent interactions. The properties of these amino acids in water and water+ electrolytes solution systems are discussed in terms of the charge , size and hydrogen bonding effect.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - Volumetric and Viscometric Studies of Solute –Solvent and Solute-Solute Interactions of Glycine in Aqueous in Aqueous Electrolytes at 30oC
    AU  - Yasmin Akhtar
    Y1  - 2014/11/22
    PY  - 2014
    N1  - https://doi.org/10.11648/j.ijsts.s.2015030102.12
    DO  - 10.11648/j.ijsts.s.2015030102.12
    T2  - International Journal of Science, Technology and Society
    JF  - International Journal of Science, Technology and Society
    JO  - International Journal of Science, Technology and Society
    SP  - 6
    EP  - 9
    PB  - Science Publishing Group
    SN  - 2330-7420
    UR  - https://doi.org/10.11648/j.ijsts.s.2015030102.12
    AB  - Densities and viscosities of Glycine in aqueous NaCl and MgCl2(0.02& 0.06 M ) solutions have been determined experimentally at 30oC.The results obtained from density and viscosity measurement  have been used to calculate A and  B coefficients and free energies of activation of viscous flow of solvent Δ µ10# and    solute Δ µ20# .The results are discussed in terms of the dehydration effect of the electrolytes upon the amino acids and weak solute- solute and strong solute- solvent interactions. The properties of these amino acids in water and water+ electrolytes solution systems are discussed in terms of the charge , size and hydrogen bonding effect.
    VL  - 3
    IS  - 1-2
    ER  - 

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Author Information
  • Department of chemistry, University of Tabuk, Tabuk, Saudi Arabia

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